Carbon monoxide hydrogenation over alkali-promoted Rh/Al2O3, Rh/V2O3/SiO2 and Rh/ThO2/SiO2

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Carbon monoxide hydrogenation over alkali-promoted Rh/Al2O3, Rh/V2O3/SiO2 and Rh/ThO2/SiO2

Addition of Li, Na, K and Cs to a 1.5 wt% Rh/Al,O, catalyst resulted in a decrease of the hydrocarbon formation rate, while the methanol formation rate was almost unaffected. The overall result is an increased oxygenate selectivity at a decreased total activity. The oxo-selectivity increased in the order unpromoted < Li < Na< K < Cs. The results suggest that the main role of the alkali promoter...

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ژورنال

عنوان ژورنال: Applied Catalysis

سال: 1987

ISSN: 0166-9834

DOI: 10.1016/s0166-9834(00)82427-6